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Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor
Journal article

Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor

Daniel Nieto, Ana Ma González-Vadillo, Sonia Bruña, César J Pastor, Angel E Kaifer and Isabel Cuadrado
Chemical communications (Cambridge, England), Vol.47(37), pp.10398-10400
2011-10-07
DOI: https://doi.org/10.1039/c1cc13704b
PMID: 21845259

Abstract

Oxidation-Reduction Nitriles - chemistry Phosphates - chemistry Chemistry Techniques, Analytical - instrumentation Ligands Organometallic Compounds - chemistry Ferrous Compounds - chemistry Catalysis Phosphates - analysis Amidines - chemistry Platinum - chemistry
A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(II)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H(2)PO(4)(-).

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Collaboration types
Domestic collaboration
International collaboration
Citation topics
2 Chemistry
2.53 Polymers & Macromolecules
2.53.1451 Dendrimers
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry

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