Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms

Tamás Kégl; George C Fortman; Manuel Temprado; Carl D Hoff

doi:10.1002/9780470602577.ch10

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Book chapter

Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms

Tamás Kégl, George C Fortman, Manuel Temprado and Carl D Hoff

Physical Inorganic Chemistry, pp.429-494

John Wiley & Sons, Inc

2010-04-07

DOI: https://doi.org/10.1002/9780470602577.ch10

Abstract

organometallic radicals and reactivity and matrix isolation spectroscopy

organometallic radicals ‐ thermodynamics, kinetics and reaction mechanisms

Werner‐type coordination compounds ‐ orbital splitting and pairing energies based on ligand field theory

This chapter contains sections titled: Introduction Historical Spectroscopic Techniques Used to Characterize Metal Radicals Representative Organometallic Radicals and Reactivity Ligand‐Centered Reactivity Spin State Change Effects Computational Studies of Radical Systems Conclusion and Future Directions References

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Title: Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms
Creators: Tamás Kégl - University of Pannonia
George C Fortman - University of Miami
Manuel Temprado - University of Miami
Carl D Hoff - University of Miami
Contributors: Andreja Bakac (Editor)
Publication Details: Physical Inorganic Chemistry, pp.429-494
Publisher: John Wiley & Sons, Inc; Hoboken, NJ, USA
Number of pages: 66
Academic Unit: A&S - Chemistry; College of A&S
Language: English
Resource Type: Book chapter
Record Identifier: 991031719220602976