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A Dynamic Rearrangement of a Metal Cluster in a Process that Closely Resembles the Hopping Mechanism of Adatom Diffusion on Metal Surfaces
Journal article   Peer reviewed

A Dynamic Rearrangement of a Metal Cluster in a Process that Closely Resembles the Hopping Mechanism of Adatom Diffusion on Metal Surfaces

Richard D Adams, Burjor Captain, Wei Fu, Perry J Pellechia and Mark D Smith
Angewandte Chemie (International ed.), Vol.41(11), pp.1951-1953
2002-06-03
DOI: https://doi.org/10.1002/1521-3773(20020603)41:11<1951::AID-ANIE1951>3.0.CO;2-T
PMID: 19750643

Abstract

ruthenium cluster compounds platinum rearrangements
Metal in motion: The reaction of [Ru5(CO)15(μ5‐C)] with [Pt(PtBu3)2] yields [Ru5Pt(PtBu3)(CO)15(C)]. The product exists as two isomers, an open and a closed form, which interconvert rapidly on the NMR timescale by a process that resembles the diffusion of metal adatoms across a metal surface (see scheme; at 20°C the rate=24 000 s−1).

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Citation topics
2 Chemistry
2.1 Synthesis
2.1.32 PPh3
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry

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