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A Redox-switchable Molecular Receptor Based on Anthraquinone
Journal article   Peer reviewed

A Redox-switchable Molecular Receptor Based on Anthraquinone

Ernesto Abel, Rene Castro, Ian M McRobbie, Len Barbour, Jerry L Atwood, Angel E Kaifer and George W Gokel
Supramolecular chemistry, Vol.9(3), pp.199-202
1998-08-01

Abstract

The reaction of two equivalents each of bisphenol A with 1,5-dichloroanthraquinone in the presence of base leads to a molecular box designed to be electroactive. The compound is fully characterized, it exhibits reversible redox behavior, and its solid state structure has been obtained. Two molecules of toluene are present in the crystal lattice but these are not located within the receptor's cavity. Evidence for an interaction of ferrocene (guest) with a precursor to the molecular box is described.

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Collaboration types
Domestic collaboration
Citation topics
2 Chemistry
2.59 Pigments, Sensors & Probes
2.59.684 Ion-Selective Electrodes
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry

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