Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane

Deborah A Gustowski; Vincent J Gatto; Angel Kaifer; Luis Echegoyen; Robert E Godt; George W Gokel

doi:10.1039/C39840000923

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Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane

Deborah A Gustowski, Vincent J Gatto, Angel Kaifer, Luis Echegoyen, Robert E Godt and George W Gokel

Journal of the Chemical Society, Chemical Communications, (14), pp.923-925

1984

DOI: https://doi.org/10.1039/C39840000923

Abstract

Azobenzenes are shown for the first time to exhibit substantial Li + and Na + cation effects on their electrochemical behaviour, and although K + does not interact with Ar-N&z.dbd6;N-Ar, or its reduced form, a srong interaction is observed when K + is bound as a cryptate complex.

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Title: Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane
Creators: Deborah A Gustowski
Vincent J Gatto
Angel Kaifer
Luis Echegoyen
Robert E Godt
George W Gokel
Publication Details: Journal of the Chemical Society, Chemical Communications, (14), pp.923-925
Number of pages: 3
Academic Unit: A&S - Chemistry
Resource Type: Journal article
Record Identifier: 991031615226502976