Sign in
Back
Coordination RC6H4S(CH2)(8)SC6H4R/(CuI)(n) Polymers (R (n) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference
Journal article   Peer reviewed

Coordination RC6H4S(CH2)(8)SC6H4R/(CuI)(n) Polymers (R (n) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference

Pierre D. Harvey, Antoine Bonnot, Antony Lapprand, Carsten Strohmann and Michael Knorr
Macromolecular rapid communications, Vol.36(7), pp.654-659
2015-04-01
DOI: https://doi.org/10.1002/marc.201400659
PMID: 25628232

Abstract

Physical Sciences Polymer Science Science & Technology
Under identical conditions, CuI reacts with PhS(CH2)(8)SPh and p-TolS(CH2)(8)STol-p affording, respectively, a luminescent 1D coordination polymer [Cu4I4{(2)-PhS(CH2)(8)SPh}(2)](n) (1) and an unprecedented 2D network [Cu8I8{(2)-p-TolS(CH2)(8)STol-p}(3)(MeCN)(2)](n) (2), which incorporate closed-cubane Cu4I4 and octanuclear Cu8I8 clusters of as connecting nodes. Their thermal and photophysical properties exhibit notable differences.

Metrics

1 Record Views
19 Times Cited - Web of Science

InCites Highlights

These are selected metrics from InCites Benchmarking & Analytics tool, related to this output

Collaboration types
Domestic collaboration
International collaboration
Citation topics
2 Chemistry
2.22 Inorganic & Nuclear Chemistry
2.22.14 Hydrogen Bonds
Web Of Science research areas
Polymer Science
ESI research areas
Chemistry

UN Sustainable Development Goals (SDGs)

This output has contributed to the advancement of the following goals:

#3 Good Health and Well-Being

Source: InCites

Details