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Heavy cation effect on intersystem crossing between triplet and singlet phenylacyl and benzyl geminate radical pairs within zeolites
Journal article   Peer reviewed

Heavy cation effect on intersystem crossing between triplet and singlet phenylacyl and benzyl geminate radical pairs within zeolites

Manoj Warrier, Nicholas J Turro and V Ramamurthy
Tetrahedron letters, Vol.41(37), pp.7163-7167
2000

Abstract

radical pairs zeolite dibenzyl ketone spin
The difference in product selectivity observed between dibenzyl ketones and naphthyl esters in zeolites is due to the difference in spin of the radical pairs formed from these precursors. Heavy cations present in zeolites can enhance intersystem crossing between triplet and singlet geminate radical pairs.

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Collaboration types
Domestic collaboration
Citation topics
2 Chemistry
2.59 Pigments, Sensors & Probes
2.59.290 bpy
Web Of Science research areas
Chemistry, Organic
ESI research areas
Chemistry

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