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Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction
Journal article   Open access

Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

Pirmin A Ulmann, Adam B Braunschweig, One-Sun Lee, Michael J Wiester, George C Schatz and Chad A Mirkin
Chemical communications (Cambridge, England), (34), pp.5121-5123
2009-09-14
DOI: https://doi.org/10.1039/b908852k
PMCID: PMC3930335
PMID: 20448966

Abstract

Catalysis Ethylenediamines - chemistry Ligands Macromolecular Substances - chemical synthesis Macromolecular Substances - chemistry Manganese - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Platinum - chemistry Pyridines - chemistry
This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.
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https://doi.org/10.1039/b908852kView
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Citation topics
2 Chemistry
2.59 Pigments, Sensors & Probes
2.59.250 Cyclodextrins
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry

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