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Making a difference on excited-state chemistry by controlling free space within a nanocapsule: photochemistry of 1-(4-alkylphenyl)-3-phenylpropan-2-ones
Journal article   Peer reviewed

Making a difference on excited-state chemistry by controlling free space within a nanocapsule: photochemistry of 1-(4-alkylphenyl)-3-phenylpropan-2-ones

Arun Kumar Sundaresan and V Ramamurthy
Organic letters, Vol.9(18), pp.3575-3578
2007-08-30
DOI: https://doi.org/10.1021/ol0713990
PMID: 17665921

Abstract

Propiolactone - analogs & derivatives Molecular Structure Propiolactone - chemistry Alkanes - chemistry Nanocapsules - chemistry Photochemistry
The free space within a reaction cavity plays a determining role during the excited-state reaction of 1-(4-alkylphenyl)-3-phenylpropan-2-ones included within a capsule formed by two molecules of a deep cavity cavitand. By controlling the free space within the reaction cavity through remote alkyl substitution on the reactant ketone it is possible to control the yield of the rearrangement product shown above.

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Citation topics
2 Chemistry
2.59 Pigments, Sensors & Probes
2.59.250 Cyclodextrins
Web Of Science research areas
Chemistry, Organic
ESI research areas
Chemistry

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