PHOTOFRAGMENTATION REACTIONS OF THIOCARBONYL COMPOUNDS

K Muthuramu; V Ramamurthy

doi:10.1246/cl.1981.1261

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PHOTOFRAGMENTATION REACTIONS OF THIOCARBONYL COMPOUNDS

Journal article

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PHOTOFRAGMENTATION REACTIONS OF THIOCARBONYL COMPOUNDS

K Muthuramu and V Ramamurthy

Chemistry letters, Vol.10(9), pp.1261-1264

1981-09-05

DOI: https://doi.org/10.1246/cl.1981.1261

Abstract

Preferential yield of ring expansion and rearrangement products through α-cleavage of tetramethyl-3-thio-1,3-cyclobutanedione (1) and 3-mercapto-2,2,4-trimethyl-3-pentenoic acid β-(thio lactone) (2) involving diradical and carbene has been observed upon photolysis of 1 and 2.

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Citation topics: 2 Chemistry; 2.59 Pigments, Sensors & Probes; 2.59.290 bpy
Web Of Science research areas: Chemistry, Multidisciplinary
ESI research areas: Chemistry

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Details

Title: PHOTOFRAGMENTATION REACTIONS OF THIOCARBONYL COMPOUNDS
Creators: K Muthuramu - 1 Department of Organic Chemistry, Indian Institute of Science
V Ramamurthy - 1 Department of Organic Chemistry, Indian Institute of Science
Publication Details: Chemistry letters, Vol.10(9), pp.1261-1264
Publisher: The Chemical Society of Japan
Academic Unit: College of A&S; A&S - Chemistry
Language: English
Resource Type: Journal article
Record Identifier: 991031598408402976