STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN

Narayan Ramnath; Vaidhya Jayathertha Rao; Varadaraj Ramesh; Vaidhyanathan Ramamurthy

doi:10.1246/cl.1982.89

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STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN

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STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN

Narayan Ramnath, Vaidhya Jayathertha Rao, Varadaraj Ramesh and Vaidhyanathan Ramamurthy

Chemistry letters, Vol.11(1), pp.89-92

1982-01-05

DOI: https://doi.org/10.1246/cl.1982.89

Abstract

Singlet oxygen oxidation of dialkyl thioketones yields the corresponding ketones and in some cases sulfoxides in varying amounts. Steric considerations on the reactive zwitterionic/diradical intermediates have been invoked to rationalise the product distribution.

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Citation topics: 2 Chemistry; 2.1 Synthesis; 2.1.965 Sulfoxides
Web Of Science research areas: Chemistry, Multidisciplinary
ESI research areas: Chemistry

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Details

Title: STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN
Creators: Narayan Ramnath - 1 Department of Organic Chemistry, Indian Institute of Science
Vaidhya Jayathertha Rao - 1 Department of Organic Chemistry, Indian Institute of Science
Varadaraj Ramesh - 1 Department of Organic Chemistry, Indian Institute of Science
Vaidhyanathan Ramamurthy - 1 Department of Organic Chemistry, Indian Institute of Science
Publication Details: Chemistry letters, Vol.11(1), pp.89-92
Publisher: The Chemical Society of Japan
Academic Unit: College of A&S; A&S - Chemistry
Language: English
Resource Type: Journal article
Record Identifier: 991031600154902976