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Spectroscopic tracking of molecular transport junctions generated by using click chemistry
Journal article   Peer reviewed

Spectroscopic tracking of molecular transport junctions generated by using click chemistry

Xiaodong Chen, Adam B Braunschweig, Michael J Wiester, Sina Yeganeh, Mark A Ratner and Chad A Mirkin
Angewandte Chemie (International ed.), Vol.48(28), pp.5178-5181
2009
PMID: 19229905

Abstract

Alkynes - chemistry Azides - chemistry Fluorenes - chemistry Microscopy, Electron, Scanning Nanowires - chemistry Spectrum Analysis, Raman - methods
Click to fill the gap: The in situ modular fabrication of molecular transport junctions in nanogaps generated by on-wire lithography is achieved by using click chemistry (see picture). The formation of molecular junctions proceeds in high yields and can be used to test different molecules; the triazole group also maintains conjugation in the molecular wires. Raman spectroscopy is used to characterize the molecular assembly processes.

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Citation topics
2 Chemistry
2.167 Microelectromechanical Systems
2.167.305 Self-Assembled Monolayers
Web Of Science research areas
Chemistry, Multidisciplinary
ESI research areas
Chemistry

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