Switching a molecular shuttle on and off: simple, pH-controlled pseudorotaxanes based on cucurbit[7]uril

Vladimir Sindelar; Serena Silvi; Angel E Kaifer

doi:10.1039/b601959e

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Journal article

Switching a molecular shuttle on and off: simple, pH-controlled pseudorotaxanes based on cucurbit[7]uril

Vladimir Sindelar, Serena Silvi and Angel E Kaifer

Chemical communications (Cambridge, England), (20), pp.2185-2187

2006-05-28

DOI: https://doi.org/10.1039/b601959e

PMID: 16703149

Abstract

Cucurbit[7[uril, the wheel component in two new and structurally simple pseudorotaxanes, shuttles between the two axle termini at low pH, whereas the shuttling motion stops at higher pH, as the wheel is bound to the center of the axle.

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Citation topics: 2 Chemistry; 2.59 Pigments, Sensors & Probes; 2.59.250 Cyclodextrins
Web Of Science research areas: Chemistry, Multidisciplinary
ESI research areas: Chemistry

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Details

Title: Switching a molecular shuttle on and off: simple, pH-controlled pseudorotaxanes based on cucurbit[7]uril
Creators: Vladimir Sindelar - Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, Florida 33124-0431, USA
Serena Silvi
Angel E Kaifer
Publication Details: Chemical communications (Cambridge, England), (20), pp.2185-2187
Publisher: England
Academic Unit: A&S - Chemistry
Language: English
Resource Type: Journal article
PMID: 16703149
Record Identifier: 991031562481502976