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Toward less dependence on platinum group metal catalysts: the merits of utilizing tin
Journal article   Peer reviewed

Toward less dependence on platinum group metal catalysts: the merits of utilizing tin

Richard D Adams, Douglas A Blom, Burjor Captain, Robert Raja, John Meurig Thomas and Eszter Trufan
Langmuir, Vol.24(17), pp.9223-9226
2008-09-02
DOI: https://doi.org/10.1021/la801759d
PMID: 18690726

Abstract

Minute stoichiometric bimetallic clusters rich in tin (PtSn 2, RhSn 2, and RuSn 2) are powerful selective hydrogenation catalysts: these "molecular metallic" entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.

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64 Times Cited - Web of Science

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Collaboration types
Domestic collaboration
International collaboration
Citation topics
2 Chemistry
2.1 Synthesis
2.1.32 PPh3
Web Of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
ESI research areas
Chemistry

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