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Upside Down! Crystallographic and Spectroscopic Characterization of an [Fe-IV(O-syn)(TMC)(2+) Complex
Journal article   Peer reviewed

Upside Down! Crystallographic and Spectroscopic Characterization of an [Fe-IV(O-syn)(TMC)(2+) Complex

Jai Prakash, Gregory T. Rohde, Katlyn K. Meier, Eckard Muenck and Lawrence Que
Inorganic chemistry, Vol.54(23), pp.11055-11057
2015-12-07
DOI: https://doi.org/10.1021/acs.inorgchem.5b02011
PMID: 26615667

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Fe-II(TMC)(OTf)(2) reacts with 2-(BuSO2)-Bu-t-C6H4IO to afford an oxoiron(IV) product, 2, distinct from the previously reported [Fe-IV(O-anti) (TMC) (NCMe)](2+). In MeCN, 2 has a blue-shifted near-IR band, a higher nu(Fe=O), a larger Mossbauer quadrupole splitting, and quite a distinct H-1 NMR spectrum. Structural analysis of crystals grown from CH2Cl2 reveals a complex with the formulation of [Fe-IV(O)(TMC)(OTf)](OTf) and the shortest Fe-IV=O bond 1.625(4) angstrom] found to date.

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Collaboration types
Domestic collaboration
Citation topics
2 Chemistry
2.22 Inorganic & Nuclear Chemistry
2.22.1421 Hemocyanin
Web Of Science research areas
Chemistry, Inorganic & Nuclear
ESI research areas
Chemistry

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